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2014/3
Activation of methane in trifluoroacetic acid
Oil and gas processing, chemistry of oil and gas

Authors: Marina V. VISHNETSKAYA graduated from M.V. Lomonosov Moscow State University University. She is Doctor of Chemistry, Professor of the Department of Industrial Ecology of Gubkin Russian State University of Oil and Gas. She is author of over 120 scientific papers in the field of homogeneous and heterogeneous catalysis, fundamental problems of chemical engineering, chemical dynamics, reactivity and chemical kinetics. E-mail: mvvishnetskaya@mail.ru
Oleg M. SVICHKAREV graduated from Gubkin Russian State University of Oil and Gas in 2013. He is Master of Engineering and Technology. E-mail: caba_iz_ct@mail.ru
Maria S. IVANOVA graduated from Gubkin Russain State University of Oil and Gas in 2010. She is Ph.D., Associate Professor of the Department of Mining and Petroleum Engineering of the Ammosov North-Eastern Federal University in Mirny. E-mail: ims.06@mail.ru
Mikhail Y. MELNIKOV graduated from M.V. Lomonosov Moscow State University in 1969. He is Doctor of Chemistry, Professor of the Department of Chemical Kinetics of M.V. Lomonosov Moscow State University University. He is author of over 220 scientific papers. E-mail: melnikov46@mail.ru

Abstract: Activation of methane for its chemical use is an urgent task. The transformation of methane occurs with the formation of a gummy product in anhydrous trifluoroacetic acid (TFA) at room temperature and atmospheric pressure. Spiking ions with masses of 684 and 700 are observed in MALDI-TOF spectra of the dry residue of the transformation products of methane

Index UDK: УДК 541.128

Keywords: molecular oxygen activation, methane, C–C bond, trifluoroacetic acid

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